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Thanks to their outstanding hydrogen selectivity, palladium membranes have attracted extensive R&D interest. They are a potential breakthrough technology for hydrogen production and also have promising applications in the areas of thermochemical biorefining. This book summarises key research in palladium membrane technologies, with particular focus on the scale-up challenges. After an introductory chapter, Part one reviews the fabrication of palladium membranes. Part two then focuses on palladium membrane module and reactor design. The final part of the book reviews the operation of palladium membranes for synthesis gas/hydrogen production, carbon capture and other applications. - Review of manufacture and design issues for palladium membranes
- Discussion of the applications of palladium membrane technology, including solar steam reforming, IGCC plants, NGCC plants, CHP plants and hydrogen production
- Examples of the technology in operation
1. Introduction to palladium membrane technology Part One: Membrane fabrication and reactor design2. Fabrication of palladium-based membranes by magnetron sputtering3. The use of electroless plating as a deposition technology in the fabrication of palladium-based membranes4. Large-scale ceramic support fabrication for palladium membranes5. Fabrication of supported palladium alloy membranes using electroless plating techniques6. Development and application of self-supported palladium membranes7. Testing palladium membranes: methods and results8. Criteria for palladium membrane reactor design: architecture, thermal effects and autothermal design9. Simulation of palladium membrane reactors: a simulator developed in the CACHET-II project Part Two: Application of palladium membrane technology in hydrogen production, carbon capture and other applications10. Palladium membranes in solar steam reforming11. Using palladium membranes for carbon capture in integrated gasification combined cycle (IGCC) power plants12. Using palladium membranes for carbon capture in natural gas combined cycle (NGCC) power plants: process integration and techno-economics13. Using palladium membrane reformers for hydrogen production14. Operation of a palladium membrane reformer system for hydrogen production: the case of Tokyo Gas15. Using palladium membrane-based fuel reformers for combined heat and power (CHP) plants16. Review of palladium membrane use in biorefinery operations